Games
| Group stage | ||
|---|---|---|
 Italy2-0 Chile  1966-07-13, 19:30 | ||
| Chile 1-1 North Korea  1966-07-15, 19:30 | ||
 Soviet Union2-1 Chile 1966-07-20, 19:30 | ||
Manager
- Luis Álamos
Squad
- 1Pedro ArayaFW
- 2Hugo BerlyDF
- 3Carlos CamposMF
- 4Humberto CruzMF
- 5Humberto DonosoDF
- 6Luis EyzaguirreDF
- 7Elías FigueroaDF
- 8Alberto FouillouxFW
- 9Adán GodoyGK
- 10Roberto HodgeMF
- 11Honorino LandaFW
- 12Rubén MarcosMF
- 13Juan OlivaresGK
- 14Ignacio PrietoMF
- 15Jaime RamírezMF
- 16Orlando RamírezFW
- 17Leonel SánchezMF
- 18Armando TobarMF
- 19Francisco ValdésFW
- 20Alberto ValentiniDF
- 21Hugo VillanuevaDF
- 22Guillermo YávarFW