Games
| Group stage | ||
|---|---|---|
 Argentina2-1 Spain  1966-07-13, 19:30 | ||
| Spain 2-1 Switzerland  1966-07-15, 19:30 | ||
 West Germany2-1 Spain 1966-07-20, 19:30 | ||
Manager
- José Villalonga
Squad
- 1José Ángel IribarGK
- 2Manuel SanchísDF
- 3 EladioDF
- 4Luis del SolMF
- 5Ignacio ZocoMF
- 6Jesús GlaríaMF
- 7José UfarteMF
- 8 AmancioFW
- 9 MarcelinoFW
- 10Luis SuárezFW
- 11Francisco GentoFW
- 12Antonio BetancortGK
- 13Miguel ReinaGK
- 14Feliciano RivillaDF
- 15Severino ReijaDF
- 16Ferran OlivellaDF
- 17 GallegoDF
- 18 PirriMF
- 19Josep Maria FustéMF
- 20Joaquín PeiróMF
- 21 AdelardoMF
- 22Carlos LapetraFW