Games
| Round of 16 | ||
|---|---|---|
 Brazil1(3)-1(2) Chile  2014-06-28, 13:00 | ||
| Group stage | ||
| Chile 3-1 Australia  2014-06-13, 18:00 | ||
 Spain0-2 Chile 2014-06-18, 16:00 | ||
 Netherlands2-0 Chile 2014-06-23, 13:00 | ||
Manager
- Jorge Sampaoli
Squad
- 1Claudio BravoGK
- 2Eugenio MenaDF
- 3Miiko AlbornozDF
- 4Mauricio IslaMF
- 5Francisco SilvaMF
- 6Carlos CarmonaMF
- 7Alexis SánchezFW
- 8Arturo VidalMF
- 9Mauricio PinillaFW
- 10Jorge ValdiviaMF
- 11Eduardo VargasFW
- 12Cristopher ToselliGK
- 13José Manuel RojasDF
- 14Fabián OrellanaMF
- 15Jean BeausejourMF
- 16Felipe GutiérrezMF
- 17Gary MedelDF
- 18Gonzalo JaraDF
- 19José Pablo FuenzalidaMF
- 20Charles AránguizMF
- 21Marcelo DíazMF
- 22Esteban ParedesFW
- 23Johnny HerreraGK